(2R)-1-[(1R)-1-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE
(2R)-1-[(1R)-1-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE
CAS: 849924-43-2
Molecular Formula: C35H39P2.C5H5.Fe
(2R)-1-[(1R)-1-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE - Names and Identifiers
(2R)-1-[(1R)-1-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE - Physico-chemical Properties
| Molecular Formula | C35H39P2.C5H5.Fe |
| Molar Mass | 642.581 |
| Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
(2R)-1-[(1R)-1-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE - Risk and Safety
| WGK Germany | 3 |
| HS Code | 29319090 |
(2R)-1-[(1R)-1-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE - Introduction
(2R)-1-[(1R)-1-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE, also known as (2R)-1-[(1R)-1-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE. Its nature, use, method and safety information are as follows:
Nature:
The compound is an organometallic compound with far-infrared absorption properties and is soluble in organic solvents such as benzene and dimethyl dithioacetate.
Use:
As a chiral catalyst, it is often used in asymmetric catalytic reactions, such as asymmetric hydrogenation, asymmetric reduction, etc.
Preparation Method:
The compound can be obtained by a multi-step synthesis. First, ferrocene is reacted with bis (1-naphthyl) phosphine bromide to obtain ferrocenyl (1-naphthyl) phosphine, which is then reacted with sodium bromide to obtain (DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE. Next, the (DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE is reacted with dibromoethane to give 1-(DI-1-NAPHTHALENYLPHOSPHINO)ETHANE. Finally, 1-(DI-1-NAPHTHALENYLPHOSPHINO)ETHANE is reacted with di-tert-butylphosphine to give (2R)-1-[(1R)-1-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE.
Safety Information:
This compound has limited safety information, but should generally be considered hazardous to humans. During the operation, the safety operation regulations shall be observed, and appropriate protective measures shall be provided, such as wearing protective glasses, gloves, protective clothing, etc. Avoid inhalation, ingestion or contact with skin. During storage and handling, care should be taken to avoid contact with oxygen, acids or other substances that are prone to reactions.
Nature:
The compound is an organometallic compound with far-infrared absorption properties and is soluble in organic solvents such as benzene and dimethyl dithioacetate.
Use:
As a chiral catalyst, it is often used in asymmetric catalytic reactions, such as asymmetric hydrogenation, asymmetric reduction, etc.
Preparation Method:
The compound can be obtained by a multi-step synthesis. First, ferrocene is reacted with bis (1-naphthyl) phosphine bromide to obtain ferrocenyl (1-naphthyl) phosphine, which is then reacted with sodium bromide to obtain (DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE. Next, the (DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE is reacted with dibromoethane to give 1-(DI-1-NAPHTHALENYLPHOSPHINO)ETHANE. Finally, 1-(DI-1-NAPHTHALENYLPHOSPHINO)ETHANE is reacted with di-tert-butylphosphine to give (2R)-1-[(1R)-1-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE.
Safety Information:
This compound has limited safety information, but should generally be considered hazardous to humans. During the operation, the safety operation regulations shall be observed, and appropriate protective measures shall be provided, such as wearing protective glasses, gloves, protective clothing, etc. Avoid inhalation, ingestion or contact with skin. During storage and handling, care should be taken to avoid contact with oxygen, acids or other substances that are prone to reactions.
Last Update：2024-04-09 21:01:54
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Product Name: (R)-1-{(S)-2-[DI(1-Naphthyl)Phosphino]Ferrocenyl}Ethyldi-Tert.-Butylphosphine Visit Supplier Webpage Request for quotation
CAS: 849924-43-2
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
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CAS: 849924-43-2
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Wechat: 18301782025
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